Ethyl­enediammonium tetra­kis({2,2′-[ethane-1,2-diylbis(nitrilo­methyl­idyne)]diphenolato}nickel(II)) bis­(perchlorate) dimethyl­formamide monosolvate

نویسندگان

  • Gervas Assey
  • Yilma Gultneh
  • Ray J. Butcher
چکیده

The title compound, (C(2)H(10)N(2))[Ni(C(16)H(14)N(2)O(2))](4)(ClO(4))(2)·C(3)H(7)NO, crystallizes with four Ni(salen) mol-ecules {salen is 2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate}, one ethyl-enediammonium cation (actually two half-cations, each located on a center of inversion), two perchlorate anions and one dimethyl-formamide solvent mol-ecule in the asymmetric unit. Each Ni(II) cation in the Ni(salen) complex is four-coordinated by two imine N atoms and two phenolate O atoms from the tetra-dentate ligand. The Ni(salen) units form parallel slipped stacks with Ni⋯Ni separations of 3.4541 (4) and 3.6442 (6) Å. The crystal packing is stabilized by inter-molecular hydrogen bonds between the ammonium H atoms and the perchlorate and salen O atoms, which generate a three-dimensional structure.

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عنوان ژورنال:

دوره 66  شماره 

صفحات  -

تاریخ انتشار 2010